Statistics for occurrence #1 of “United States of America” in entry federal-union-the-john-fiske of Harper's Encyclopedia of United States History:

... advanced stage of elaboration, though in a part of Greece which had been held of little account in the great days of Athens and Sparta. Between the Achaian federation, framed in 274 B. C., and the United States of America , there are some interesting points of resemblance which have been elaborately discussed by Mr. Freeman, in his . About the same time the Aetolian League came into prominence in the north. Both th...
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