Statistics for occurrence #1 of “Mrs. Madison” in entry barker-jacob of Harper's Encyclopedia of United States History:

...pposition to Judge Kent, and was sustained by the court. During the War of 1812 his ships were all captured. Being in Washington, D. C., during its sack by the British (August, 1814), he assisted Mrs. Madison in saving Stuart's portrait of Washington, then hanging in the President's house, which was set on fire a few hours later. Barker was a banker, a dealer in stocks, and a general and shrewd financie...
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