Statistics for occurrence #1 of “Washington, D. C.” in chapter 1 of Waitt, Ernest Linden, History of the Nineteenth regiment, Massachusetts volunteer infantry , 1861-1865:

... Commonwealth of Massachusetts, A. G. O., Boston, Aug. 26, 1861. Col. Hinks, Commanding, 19th Regt. Mass. Vols. Sir: You are directed to proceed with your command on Tuesday, 27th inst., to Washington, D. C. When you arrive there, you will report yourself to Brig. Gen. Mansfield U. S.A. and await orders. Quartermaster General Reed is directed to furnish you with transportation for your Regiment and yo...
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